Concentrated aqueous sulphuric acid is 98% H2SO4by mass and has a  density of 1.80 g mL-1.Volume of acid required to make one litre of 0.1 M H2SO4 solution is:

  • 11.10 mL

  • 16.65 mL

  • 22.20 mL

  • 22.20 mL


D.

22.20 mL


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A 0.0020 m aqueous solution  of an ionic compound Co(NH3)5(NO2)Cl freezes at -0.00732o C . Number of moles of ions which 1 mol of ionic compound produces on being dissolved in water will be (kf = - 1.86o C/m)

  • 2

  • 3

  • 4

  • 4


A.

2

Given,

molality = 0.0020 m

Δ Tf = 0o C -0.007320 C

kf = 1.86 oC/m


ΔTf = i.kf x m

i = ΔTf/ kf x m

= 0.00732/1.82 x 0.0020

= 1.92 = 2

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A solution of sucrose (molar mass = 342 g mol-1) has been prepared by dissolving 68.5 g of sucrose in 1000 g of water. The freezing point of the solution obtained will be (kf for water = 1.86 K kg mol-1)

  • -0.372o C

  • -0.520o C

  • +0.372o C

  • +0.372o C


A.

-0.372o C

Depression in freezing point,


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What is the [OH-] in the final solution prepared by mixing 20.0 mL of 0.50 M HCl with 30.0mL of 0.10 Ba(OH)2?

  • 0.10 M

  • 0.40 M

  • 0.0050 M

  • 0.0050 M


A.

0.10 M

Number of milliequivalents of HCl = 2 x 0.050 x 1 = 1
Number  of milliequivalents of Ba(OH)2 = 2 x 30 x 0.10 = 6
[OH]- of final soluton 

milliequivalent of Ba(OH)2 



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25.3 g of sodium carbonate, Na2CO3 is dissolved in enough water to make 250 mL of solution. If sodium carbonate dissociates completely molar concentration of sodium ion, Na+ and carbonate ion, CO32- are respectively (Molar mass of Na2CO3 = 106 g mol-1)

  • 0.955 M and 1.910 M

  • 1.910 M and 0.955 M 

  • 1.90 M and 1.910 M 

  • 1.90 M and 1.910 M 


B.

1.910 M and 0.955 M 

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